Effect of potential difference between the central and terminal metals on the electron communication in an Fe–Ru–Fe cyanidometal-bridged mixed valence system-Reference-Cited by-同舟云学术

Effect of potential difference between the central and terminal metals on the electron communication in an Fe–Ru–Fe cyanidometal-bridged mixed valence system

Published:2022 Issue:18 Volume:9 Page:4732-4740
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Yang Yu-Ying¹,Zhu Xiao-Quan¹²,Wang Yong³^ORCID,Wu Xin-Tao¹^ORCID,Sheng Tian-Lu¹^ORCID

Affiliation:

1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Science, 350002 Fuzhou, Fujian, China

2. Department of Criminal Investigation, Fujian Police College, 350007 Fuzhou, Fujian, China

3. Hubei Key Laboratory of Drug Synthesis and Optimization, College of Chemical Engineering and Pharmacy, Jingchu University of Technology, Jinmen, Hubei 444800, China

Abstract

In the Fe–Ru–Fe mixed valence system, the change of the donor and accepter can affect potential difference (energy difference) between bridge and terminal redox centers. This change has an effect on the electron communication.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D2QI00909A

Reference36 articles.

1. Direct approach to measuring the Franck-Condon barrier to electron transfer between metal ions

2. Mixed-valence molecules: Electronic delocalization and stabilization

3. Optical transitions of symmetrical mixed-valence systems in the Class II–III transition regimeElectronic supplementary information (ESI) is available: derivation of eqn. (39c), table summarizing the relationships between band maxima and band widths predicted by the two-state model and table of spectral properties of mixed-valence ruthenium(II)/(III) bridged by pyrazine and dicyanamide. See http://www.rsc.org/suppdata/cs/b0/b008034i/