An organo-functionalized metal–oxide cluster, [VIV6O6{(OCH2CH2)2N(CH2CH2OH)}6], with Anderson-like structure

Author:

Li H.1234,Swenson L.1234,Doedens R. J.5674,Khan M. I.1234

Affiliation:

1. Department Chemistry

2. Illinois Institute of Technology

3. Chicago

4. USA

5. Department of Chemistry

6. University of California

7. Irvine

Abstract

The polyoxovanadium cluster compound, [VIV6O6{(OCH2CH2)2N(CH2CH2OH)}6], is the isopolyoxovanadium analogue to cationic heteropolyoxovanadium species, such as [MVIV6O6{(OCH2CH2)2N(CH2CH2OH)}6]+ (M = Li, Na). These isopolyoxovanadium and heteropolyoxovanadium clusters represent the first reported isopoly-heteropoly analogues in the polyoxometalate field.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference37 articles.

1. M. T. Pope , Heteropoly and Isopoly Oxometalates, Springer Verlag, West Berlin, 1983

2. Present General Status of Understanding of Heteropoly Electrolytes and a Tracing of Some Major Highlights in the History of Their Elucidation

3. I. V. Kozhevnikov , Catalysis by Polyoxometalates: Catalysts for Fine Chemical Synthesis 2, John Wiley & Sons, West Sussex, England, 2002, ch. 2, pp. 9–45

4. J. B. Moffat , Metal-Oxygen Clusters: The Surface and Catalytic Properties of Heteropoly Oxometalates, Kluwer Academic Publishers, New York, 2001, ch. 5, pp. 41–69

5. J. B. Moffat , Metal-Oxygen Clusters: The Surface and Catalytic Properties of Heteropoly Oxometalates, Kluwer Academic Publishers, New York, 2001, ch. 8, pp. 143–174

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