The role of reducibility vis-à-vis oxygen vacancies of doped Co3O4/CeO2 in the oxygen evolution reaction

Author:

Roy Saraswati1,Dahiya Preeti2,Mandal Tapas Kumar23,Roy Sounak14ORCID

Affiliation:

1. Department of Chemistry, Birla Institute of Technology and Science Pilani, Hyderabad Campus, Hyderabad-500078, India

2. Department of Chemistry, Indian Institute of Technology Roorkee, Roorkee – 247 667, India

3. Centre for Nanotechnology, Indian Institute of Technology Roorkee, Roorkee – 247 667, India

4. Materials Center for Sustainable Energy & Environment, Birla Institute of Technology and Science Pilani, Hyderabad Campus, Hyderabad – 500078, India

Abstract

CeO2 aids Ce4+ → Ce3+ reduction, facilitating Co2+ → Co3+ oxidation in Co3O4 during OER's positive potential. Intermediate Co3+ lowers activation energy, boosting OER kinetics.

Funder

Birla Institute of Technology and Science, Pilani

Publisher

Royal Society of Chemistry (RSC)

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