Unveiling the formation 1 : 2 supramolecular complexes between cucurbit[7]uril and a cationic calix[4]arene derivative

Author:

Pessêgo Márcia12345,Mendoza Johan678910ORCID,da Silva José Paulo11121314,Basílio Nuno678910ORCID,Garcia-Rio Luis12345ORCID

Affiliation:

1. Departamento de Química Física

2. Centro de Investigación en Química Biolóxica e Materiais Moleculares (CIQUS)

3. Universidade de Santiago de Compostela

4. 15782 Santiago de Compostela

5. Spain

6. Laboratório Associado para a Química Verde (LAQV)

7. Rede de Química e Tecnologia (REQUIMTE)

8. Departamento de Química

9. Faculdade de Ciências e Tecnologia

10. Universidade NOVA de Lisboa

11. CCMAR-Centre of Marine Sciences

12. University of Algarve

13. 8005-139 Faro

14. Portugal

Abstract

The formation of host–guest complexes between cucurbit[7]uril (CB7) and a tetracationic calix[4]arene derivative in the so-called cone conformation was investigated by 1H NMR, DOSY NMR, isothermal titration calorimetry and ESI-MS.

Funder

Faculdade de Ciências e Tecnologia, Universidade Nova de Lisboa

Ministerio de Ciencia e Innovación

European Regional Development Fund

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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