Dye–polyoxometalate coordination polymer as a photo-driven electron pump for photocatalytic radical coupling reactions

Author:

Ming Zheng123,Zhang Tiexin1ORCID,Tian Wenming4,Li Jianing1,Liu Zhenhui1,Liu Renhai1,Liu Zhongmin23ORCID,Duan Chunying12ORCID

Affiliation:

1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116024, P. R. China

2. Zhang Dayu College of Chemistry, Dalian University of Technology, Dalian 116024, P. R. China

3. National Engineering Laboratory for Methanol to Olefins, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, P. R. China

4. State Key Laboratory of Molecular Reaction Dynamics and Dynamics Research Center for Energy and Environmental Materials, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China

Abstract

Coordination polymer containing triphenylamine and polyoxometalate photoinduced long-lived charge-separation pairs, which unidirectionally pumped multiple electrons from external electron donors to acceptors, furnishing value-added radical couplings.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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