The “electron crystal” behavior in copper chalcogenides Cu2X (X = Se, S)

Author:

Sun Yongxing12345,Xi Lili12346,Yang Jiong1234ORCID,Wu Lihua1234,Shi Xun67894,Chen Lidong67894,Snyder Jeffrey10111213,Yang Jihui14151613,Zhang Wenqing12345

Affiliation:

1. Materials Genome Institute

2. Shanghai University

3. Shanghai 200444

4. China

5. School of Materials Science and Engineering

6. State Key Laboratory of High Performance Ceramics and Superfine Microstructure

7. Shanghai Institute of Ceramics

8. Chinese Academy of Sciences

9. Shanghai 200050

10. Department of Materials Science and Engineering

11. Northwestern University

12. Evanston

13. USA

14. Material Science and Engineering Department

15. University of Washington

16. Seattle

Abstract

In Cu2Se, the structural fluctuation of the Cu sites have minor effects on the electronic structures around valence band maximum. The electrical transport properties of Cu2Se are mainly determined by the Se sublattice; Cu atoms serve as the carrier reservoirs.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Renewable Energy, Sustainability and the Environment,General Chemistry

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