What does it take to induce equilibrium in bidirectional energy transfers?-Reference-Cited by-同舟云学术

What does it take to induce equilibrium in bidirectional energy transfers?

Published:2018 Issue:20 Volume:20 Page:13682-13692
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Gao Di¹²³⁴^ORCID,Aly Shawkat M.¹²³⁴,Karsenti Paul-Ludovic¹²³⁴,Harvey Pierre D.¹²³⁴^ORCID

Affiliation:

1. Departement de chimie

2. Université de Sherbrooke

3. Sherbrooke

4. Canada

Abstract

Two dyads built with a co-facial slipped bis(zinc(ii)porphyrin), a free base and a bridge, [Zn₂]–bridge–[Fb] (bridge = C₆H₄CC, 1 and C₆H₄CCC₆H₄, 2), exhibit S₁ energy equilibrium [Zn₂]* ↔ [Fb]* at 298 K, an extremely rare situation, which depends on the degree of MO coupling between the units.

Funder

Natural Sciences and Engineering Research Council of Canada

Fonds de Recherche du Québec - Nature et Technologies

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2018/CP/C7CP07879J

Reference70 articles.

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4. Rhenium-Linked Multiporphyrin Assemblies:Synthesis and Properties

5. Multiporphyrinic Cages: Architectures and Functions

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