Thermodynamic versus non-equilibrium stability of palmitic acid monolayers in calcium-enriched sea spray aerosol proxy systems

Author:

Wellen Rudd Bethany A.1234,Vidalis Andrew S.1234,Allen Heather C.1234ORCID

Affiliation:

1. Department of Chemistry & Biochemistry

2. The Ohio State University

3. Columbus

4. USA

Abstract

Calcium ions bind to palmitic acid monolayers at the air–aqueous interface resulting in changes of both thermodynamic and non-equilibrium stability.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference89 articles.

1. O. Boucher , D.Randall , P.Artaxo , C.Bretherton , G.Feingold , P.Forster , V.-M.Kerminen , Y.Kondo , H.Liao and U.Lohmann , Clouds and Aerosols, in Climate Change: The Physical Science Basis. Contribution of Working Group I to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change , ed. T. F. Stocker, D. Qin, G.-K. Plattner, M. Tignor, S. K. Allen and J. Boschung, et al. , Cambridge University Press, New York, NY, USA , 2013

2. B. J. Finlayson-Pitts and J. N.Pitts Jr. , Chemistry of the Upper and Lower Atmosphere , Academic Press , San Diego , 2000

3. Sea-to-air transfer of surface-active organic compounds by bursting bubbles

4. Film drop production as a function of bubble size

5. Selectivity Across the Interface: A Test of Surface Activity in the Composition of Organic-Enriched Aerosols from Bubble Bursting

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