Intramolecular donor-stabilized tetra-coordinated germanium(<scp>iv</scp>) di-cations and their Lewis acidic properties-Reference-Cited by-同舟云学术

Intramolecular donor-stabilized tetra-coordinated germanium(iv) di-cations and their Lewis acidic properties

Published:2023 Issue:47 Volume:14 Page:13755-13764
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Peddi Balakrishna¹,Khan Souvik¹,Gonnade Rajesh G.²^ORCID,Yildiz Cem B.³^ORCID,Majumdar Moumita¹^ORCID

Affiliation:

1. Department of Chemistry, Indian Institute of Science Education and Research, Pune, Dr. Homi Bhabha Road, Pashan, Pune-411008, Maharashtra, India

2. Physical and Materials Chemistry Division, CSIR-National Chemical Laboratory, Pune-411008, Maharashtra, India

3. Department of Aromatic and Medicinal Plants, Aksaray University, 68100 Aksaray, Türkiye

Abstract

Intramolecular phosphine-stabilized tetra-coordinated Ge(iv) di-cations are established. Dispersed charges lead to Si–H activation initially at the P-site, which ultimately migrates to the Ge-site due to geometric constraint empowered Lewis acidity.

Funder

Science and Engineering Research Board

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC03717G

Reference92 articles.

1. A Germanium(II)-Centered Dication

2. A Cryptand-Encapsulated Germanium(II) Dication

3. Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N-heterocyclic carbene)borate Ligand

4. Cationic Crown Ether Complexes of Germanium(II)

5. Germanium(II) Dications Stabilized by Azamacrocycles and Crown Ethers

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