In situ-DRIFTS study: influence of surface acidity of rhenium-based catalysts in the metathesis of various olefins for propylene production
Author:
Affiliation:
1. Center of Excellence on Catalysis and Catalytic Reaction Engineering
2. Department of Chemical Engineering
3. Faculty of Engineering
4. Chulalongkorn University
5. Bangkok 10330
6. SCG Chemicals Co., Ltd
7. Bangkok 10800
8. Thailand
Abstract
Various olefins including 1- and 2-butene, 2-pentene, and ethylene were used as the reactants for producing propylene by self- and cross-metathesis reactions at 60 °C on supported Re-based catalysts (4 wt% Re).
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemical Engineering,General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2017/RA/C7RA06181A
Reference28 articles.
1. J. S. Plotkin, The Propylene Quandary, https://www.acs.org/content/acs/en/pressroom/cutting-edge-chemistry/the-propylene-quandary.html, accessed August 8, 2016
2. K. J. Ivin and J. C.Mol, Olefin Metathesis and Metathesis Polymerization, Academic Press, London, 1997
3. Olefin metathesis over supported rhenium oxide catalysts
4. Industrial applications of olefin metathesis
5. Activity of supported Re2O7 catalysts for the metathesis of methyl oleate
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