Using silyl protecting group to enable post-deposition C–C coupling reactions of alkyne-functionalized N-heterocyclic carbene monolayers on Au surfaces-Reference-Cited by-同舟云学术

Using silyl protecting group to enable post-deposition C–C coupling reactions of alkyne-functionalized N-heterocyclic carbene monolayers on Au surfaces

Published:2021 Issue:43 Volume:57 Page:5342-5345
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Berg Iris¹²³⁴,Hale Lillian⁵⁶⁷⁸⁹,Carmiel-Kostan Mazal¹²³⁴,Toste F. Dean⁵⁶⁷⁸⁹^ORCID,Gross Elad¹²³⁴^ORCID

Affiliation:

1. Institute of Chemistry and The Centre for Nanoscience and Nanotechnology

2. The Hebrew University

3. Jerusalem 91904

4. Israel

5. Department of Chemistry

6. University of California

7. Berkeley

8. California 94720

9. USA

Abstract

Alkyne-functionalized NHC ligands were protected by TIPS group that enabled surface-anchoring of NHCs with chemically-sensitive functionality and providing access, following TIPS removal, to on-surface Sonogashira cross–coupling reactions.

Funder

H2020 European Research Council

Ministry of Science and Technology, Israel

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CC/D1CC01271A

Reference40 articles.

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5. N-Heterocyclic carbenes as “smart” gold nanoparticle stabilizers: State-of-the art and perspectives for biomedical applications

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