Keggin-type polyoxometalate 1 : 1 complexes of Pb(ii) and Bi(iii): experimental, theoretical and luminescence studies
Author:
Affiliation:
1. Nikolaev Institute of Inorganic Chemistry
2. Russia
3. International Tomography Center
4. Novosibirsk
5. Novosibirsk State University
Abstract
Bi3+ and Pb2+ can be coordinated by a monolacunary Keggin-type [PW11O39]7− anion producing photoluminescent naked [PW11O39Bi]4− and [PW11O39Pb]5− anions.
Funder
Centre National de la Recherche Scientifique
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT00499A
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