Subtle changes in hydrogen bond orientation result in glassification of carbon capture solvents

Author:

Bañuelos José Leobardo123ORCID,Lee Mal-Soon4563,Ngyuen Manh-Thuong4563,Zhang Difan4563,Malhotra Deepika7563,Cantu David C.4563,Glezakou Vassiliki-Alexandra4563,Rousseau Roger4563,Headen Thomas F.89101112ORCID,Dalgliesh Robert M.89101112,Heldebrant David J.756313ORCID,Graham Trent R.456313ORCID,Han Kee Sung4563ORCID,Saunders Steven R.1314153ORCID

Affiliation:

1. The University of Texas at El Paso

2. El Paso

3. USA

4. Physical Sciences Division

5. Pacific Northwest National Laboratory

6. Richland

7. Energy Processes and Materials Division

8. ISIS Neutron and Muon Source

9. Rutherford Appleton Laboratory

10. Harwell Campus

11. Didcot OX11 0QX

12. UK

13. The Gene and Linda Voiland School of Chemical Engineering and Bioengineering

14. Washington State University

15. Pullman

Abstract

Multidisciplinary experimental and theoretical study highlighting the molecular-scale structural and dynamic properties of CO2 capture solvents during a temperature-, time- and CO2-loading-dependent metastable/glassy transition.

Funder

U.S. Department of Energy

National Science Foundation

Horizon 2020 Framework Programme

Chemical Sciences, Geosciences, and Biosciences Division

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Reference58 articles.

1. Climate Change 2014 Mitigation of Climate Change, Working Group III Contribution to the Fifth Assessment Report of the Intergovernmental Panel on Climate Change, https://www.ipcc.ch/site/assets/uploads/2018/02/ipcc_wg3_ar5_full.pdf

2. Global Carbon Budget 2019

3. Carbon capture and storage (CCS): the way forward

4. A. L. Kohl and R. B.Nielsen , in “Preface” in Gas Purification , ed. A. L. Kohl and R. B. Nielsen , Gulf Professional Publishing , Houston , 5th edn, 1997 , pp. vii–viii 10.1016/B978-088415220-0/50000-8

5. Carbon Capture & Sequestration Technologies at MIT, Petra Nova W.A. Parish Fact Sheet: Carbon Dioxide Capture and Storage Project, https://sequestration.mit.edu/tools/projects/wa_parish.html , 2016, accessed on January 20, 2017

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