Catalytic transfer hydrogenation of azobenzene by low-valent nickel complexes: a route to 1,2-disubstituted benzimidazoles and 2,4,5-trisubstituted imidazolines-Reference-Cited by-同舟云学术

Catalytic transfer hydrogenation of azobenzene by low-valent nickel complexes: a route to 1,2-disubstituted benzimidazoles and 2,4,5-trisubstituted imidazolines

Published:2016 Issue:25 Volume:45 Page:10389-10401
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Zurita Daniel A.¹²³⁴,Flores-Alamo Marcos¹²³⁴,García Juventino J.¹²³⁴

Affiliation:

1. Facultad de Quimica

2. Universidad Nacional Autonoma de Mexico

3. Mexico City 04510

4. Mexico

Abstract

The one-pot synthesis of 1,2-disubstituted benzimidazoles by the transfer hydrogenation of azobenzene, using benzylamine as a hydrogen donor is reported, catalyzed by 2 mol% of [Ni(COD)₂] : dippe.

Funder

Dirección General Asuntos del Personal Académico, Universidad Nacional Autónoma de México

Consejo Nacional de Ciencia y Tecnología

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT01674J

Reference90 articles.

1. Hydrogenation of single and multiple N–N or N–O bonds by Ru(II) catalysts in homogeneous phase

2. Catalytic Reduction of Azo Types of Compounds1