Intrinsic bimetallic cations regulating band centers and reactive sites for boosting CO2 photoreduction

Author:

Wang Jingjing12,Chen Fang1,Liu Qing3,Huang Hongwei1ORCID

Affiliation:

1. Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences (Beijing), Beijing 100083, China

2. Key Laboratory of Ecological Environment and Information Atlas, Fujian Provincial University, Putian 351100, China

3. Fujian Provincial Key Laboratory of Ecology-Toxicological Effects and Control for Emerging Contaminants, College of Environmental and Biological Engineering, Putian University, Putian 351100, China

Abstract

Intrinsic bimetallic cation regulation strategy achieves precise modulation of the band center and catalytic sites of CdBiO2Br. The optimal Cd0.46Bi1.36O2Br shows strong electron reducibility and interfacial charge mobility for efficient CO2 photoreduction.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

Publisher

Royal Society of Chemistry (RSC)

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