Understanding M–ligand bonding and mer-/fac-isomerism in tris(8-hydroxyquinolinate) metallic complexes-Reference-Cited by-同舟云学术

Understanding M–ligand bonding and mer-/fac-isomerism in tris(8-hydroxyquinolinate) metallic complexes

Published:2016 Issue:24 Volume:18 Page:16555-16565
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Lima Carlos F. R. A. C.¹²³⁴⁵^ORCID,Taveira Ricardo J. S.¹²³⁴⁵,Costa José C. S.¹²³⁴⁵^ORCID,Fernandes Ana M.⁶⁷⁸⁵,Melo André⁹²³⁴⁵,Silva Artur M. S.⁶⁷⁸⁵,Santos Luís M. N. B. F.¹²³⁴⁵

Affiliation:

1. CIQ

2. Departamento de Química e Bioquímica

3. Faculdade de Ciências da Universidade do Porto

4. Porto

5. Portugal

6. Department of Chemistry & QOPNA

7. University of Aveiro

8. Aveiro

9. LAQV-REQUIMTE

Abstract

mer-/fac-Isomerism in tris(8-hydroxyquinolinate) complexes is ruled by the interplay between steric and bonding factors. The M–ligand bond has strong covalent character and allows for through-ligand electron delocalization.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CP/C6CP02608G

Reference60 articles.

1. Metal−Alq3 Complexes: The Nature of the Chemical Bonding

2. Charge Transport Properties of Tris(8-hydroxyquinolinato)aluminum(III): Why It Is an Electron Transporter

3. High-Efficiency Tris(8-hydroxyquinoline)aluminum (Alq3) Complexes for Organic White-Light-Emitting Diodes and Solid-State Lighting