Temperature effects on the spatial distribution of electrolyte mixtures at the aqueous liquid–vapor interface
Author:
Affiliation:
1. Department of Chemistry
2. Wheaton College
3. Wheaton
4. USA
5. Department of Chemistry and Chemical Theory Center
6. University of Minnesota
7. Minneapolis
8. Department of Chemical Engineering and Materials Science
Abstract
Monte Carlo simulations indicate that an anion's propensity for interfacial adsorption increases with its size and is associated with an enthalpic gain and entropic cost for the largest anion.
Funder
Division of Chemical, Bioengineering, Environmental, and Transport Systems
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2020/CP/C9CP06729A
Reference42 articles.
1. ON THE NATURE OF IONS AT THE LIQUID WATER SURFACE
2. Simulation and Theory of Ions at Atmospherically Relevant Aqueous Liquid-Air Interfaces
3. The Surface Tension of Debye‐Hückel Electrolytes
4. Progress in Modeling of Ion Effects at the Vapor/Water Interface
5. Experiments and Simulations of Ion-Enhanced Interfacial Chemistry on Aqueous NaCl Aerosols
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