Atomically dispersed Ni as the active site towards selective hydrogenation of nitroarenes

Author:

Yang Fan1234,Wang Minjian1234,Liu Wei56789,Yang Bin1234,Wang Ying1011124,Luo Jun56789,Tang Yushu1234,Hou Liqiang1234,Li Yun1234,Li Zihui1234,Zhang Bing1234,Yang Wang1234,Li Yongfeng1234ORCID

Affiliation:

1. State Key Laboratory of Heavy oil Processing

2. China University of Petroleum (Beijing)

3. Beijing 102249

4. China

5. Center for Electron Microscopy and Tianjin Key Lab of Advanced Functional Porous Materials

6. Institute for New Energy Materials & Low-Carbon Technologies

7. School of Materials Science and Engineering

8. Tianjin University of Technology

9. Tianjin 300384

10. State Key Laboratory of Rare Earth Resource Utilization Changchun Institute of Applied Chemistry

11. Chinese Academy of Sciences

12. Changchun 130022

Abstract

Noble-metal-free catalytic hydrogenation of nitroarenes is achieved through the rational design of atomically dispersed Ni sites on N-doped porous carbon. The outstanding activity of the catalyst originates from the atomic dispersion of Ni active sites with a high Ni–N3 content.

Funder

National Natural Science Foundation of China

Science Foundation of China University of Petroleum, Beijing

Recruitment Program of Global Experts

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

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