Illuminating the multiple Lewis acidity of triaryl-boranes <i>via</i> atropisomeric dative adducts-Reference-Cited by-同舟云学术

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Illuminating the multiple Lewis acidity of triaryl-boranes via atropisomeric dative adducts

Published:2024 Issue: Volume: Page:
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kovács Benjámin¹^ORCID,Földes Tamás²^ORCID,Szabó Márk¹,Dorkó Éva²,Kótai Bianka²,Laczkó Gergely²³^ORCID,Holczbauer Tamás²,Domján Attila¹,Pápai Imre²^ORCID,Soós Tibor²^ORCID

Affiliation:

1. Centre for Structural Science, HUN-REN Research Centre for Natural Sciences, Magyar tudósok körútja 2, H-1117 Budapest, Hungary

2. Institute of Organic Chemistry, HUN-REN Research Centre for Natural Sciences, Magyar tudósok körútja 2, H-1117 Budapest, Hungary

3. Hevesy György PhD School of Chemistry, Eötvös Loránd University, P. O. Box 32, Budapest, H-1518, Hungary

Abstract

The emergence of a peculiar molecular phenomenon, the single-centered, but multiple Lewis acidity, is uncovered among Lewis acidic boranes with appropriate steric crowding and symmetry design.

Funder

Nemzeti Kutatási Fejlesztési és Innovációs Hivatal

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00925H

Reference90 articles.

1. Flexible Molecules with Defined Shape?Conformational Design

2. Conformational Control of Macrocycles by Remote Structural Modification

3. Conformational landscape of substituted prolines

4. Lasso Peptides: Exploring the Folding Landscape of Nature’s Smallest Interlocked Motifs

5. Conformations of Macrocyclic Peptides Sampled by Nuclear Magnetic Resonance: Models for Cell-Permeability

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