Combining geometric constraint and redox non-innocence within an ambiphilic PBiP pincer ligand-Reference-Cited by-同舟云学术

Combining geometric constraint and redox non-innocence within an ambiphilic PBiP pincer ligand

Published:2024 Issue:16 Volume:15 Page:6036-6043
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Coburger Peter¹,Buzanich Ana Guilherme²^ORCID,Emmerling Franziska²³^ORCID,Abbenseth Josh³^ORCID

Affiliation:

1. Department of Inorganic Chemistry, Technische Universität München, Lichtenbergstr. 4, 85747 Garching, Germany

2. Department of Materials Chemistry, Federal Institute for Materials Research and Testing, Richard-Willstätter-Str. 11, 12489 Berlin, Germany

3. Institut für Chemie, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany

Abstract

The first pincer ligand featuring a strictly T-shaped pnictogen donor moiety was synthesised. The PBiP ligand's redox activity facilitates unprecedented ambiphilic bonding of the Bi centre with transition metals through the Bi(6p) orbital.

Funder

Fonds der Chemischen Industrie

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/SC/D4SC00197D

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