Mechanistic and chemoselective insights on sp3- and sp2-C–H bond aminations: Fe- vs. Ir-based catalysis-Reference-Cited by-同舟云学术

Mechanistic and chemoselective insights on sp3- and sp2-C–H bond aminations: Fe- vs. Ir-based catalysis

Published:2021 Issue: Volume: Page:
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Wang Juping¹²³⁴^ORCID,Xiao Rongxing¹²³⁴,Zheng Kangcheng⁵⁶³⁴,Qian Li¹⁷⁴

Affiliation:

1. School of Pharmacy

2. Guangdong Pharmaceutical University

3. Guangzhou

4. P. R. China

5. School of Chemistry

6. Sun Yat-sen University

7. Youjiang Medical University for Nationalities

Abstract

The mechanisms of Fe- and Ir-catalyzed sp³- and sp²-C–H bond aminations of a styryl substrate have been studied using the BPW91 method, with an emphasis on the origin of sp³-to-sp²-C–H amination chemoselectivity.

Funder

Natural Science Foundation of Guangdong Province

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CY/D1CY00682G

Reference56 articles.

1. Engineering Chemoselectivity in Hemoprotein-Catalyzed Indole Amidation

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4. Iron-Catalyzed Amination of Strong Aliphatic C(sp3)–H Bonds

5. Mechanism of Rh2(II)-Catalyzed Indole Formation: The Catalyst Does Not Control Product Selectivity

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