[Re(CO)3Cl(C5H4ClP)2] and [Re(CO)2Cl(C5H4ClP)3]: synthesis and characterization of two novel rhenium(i) phosphinine complexes-Reference-Cited by-同舟云学术

[Re(CO)3Cl(C5H4ClP)2] and [Re(CO)2Cl(C5H4ClP)3]: synthesis and characterization of two novel rhenium(i) phosphinine complexes

Published:2016 Issue:17 Volume:6 Page:14134-14139
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Hollering Manuela¹²³⁴⁵,Reithmeier Richard O.¹²³⁴,Meister Simon¹²³⁴,Herdtweck Eberhardt⁵⁶²³⁴,Kühn Fritz E.⁵⁶²³⁴,Rieger Bernhard¹²³⁴

Affiliation:

1. WACKER-Chair of Macromolecular Chemistry

2. Technische Universität München

3. 85748 Garching b. München

4. Germany

5. Chair of Inorganic Chemistry/Molecular Catalysis

6. Catalysis Research Center

Abstract

Two novel rhenium(i) phosphinine complexes [Re(CO)₃Cl(η¹-C₅H₄ClP)₂] (1) and [Re(CO)₂Cl(η¹-C₅H₄ClP)₃] (2) were synthesized and the molecular structure of both was determined by single crystal X-ray diffraction.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C5RA25904E

Reference49 articles.

1. Transition metals in phosphinine chemistry

2. Phosphaalkene, phospholyl and phosphinine ligands: New tools in coordination chemistry and catalysis

3. P-Heterocycles as Ligands in Homogeneous Catalytic Reactions

4. Developments in the Coordination Chemistry of Phosphinines

5. Study on the aromaticity and reactivity of chlorophosphinines

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