Electrocatalytic oxidative Z/E isomerization of a stilbene favoured by the presence of an electroactive persistent radical-Reference-Cited by-同舟云学术

Electrocatalytic oxidative Z/E isomerization of a stilbene favoured by the presence of an electroactive persistent radical

Published:2020 Issue:91 Volume:56 Page:14211-14214
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Mayorga-Burrezo Paula¹²³⁴^ORCID,Sporer Christian¹²³⁴,de Sousa J. Alejandro¹²³⁴⁵^ORCID,Capra Nicola¹²³⁴^ORCID,Wurst Klaus⁶⁷⁸⁹¹⁰,Crivillers Núria¹²³⁴^ORCID,Veciana Jaume¹²³⁴^ORCID,Rovira Concepció¹²³⁴^ORCID

Affiliation:

1. Department of Molecular Nanoscience and Organic Materials

2. Institut de Ciència de Materials de Barcelona (ICMAB-CSIC)/CIBER-BBN

3. Cerdanyola

4. Spain

5. Laboratorio de Electroquímica

6. Institute of General

7. Inorganic and Theoretical Chemistry

8. University of Innsbruck

9. Center for Chemistry and Biomedicine

10. A-6020 Innsbruck

Abstract

The π-conjugation of an electroactive perchlorotriphenylmethyl (PTM˙) radical to an E/Z switchable stilbene derivative permits to demonstrate that its electrocatalytic Z → E isomerization is undoubtedly triggered by the open-shell nature of PTM˙ unit.

Funder

Ministerio de Ciencia e Innovación

Departament d'Innovació, Universitats i Empresa, Generalitat de Catalunya

Ministerio de Economía y Competitividad

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC04973E

Reference38 articles.

1. Design of Collective Motions from Synthetic Molecular Switches, Rotors, and Motors

2. Photoswitches: From Molecules to Materials

3. Taking orders from light: progress in photochromic bio-materials

4. Photochromic Materials: More Than Meets The Eye

5. Photoisomerization dynamics of stilbenes

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