Solvent-driven luminescence modulation/switching in an iridium(iii) complex containing an aldehyde group
Author:
Affiliation:
1. State Key Laboratory of Coordination Chemistry
2. School of Chemistry and Chemical Engineering
3. Nanjing University
4. Nanjing 210093
5. P. R. China
Abstract
Complex [Ir(dfppy)2(phca)]PF6 (1) containing an aldehyde group shows solvent-driven luminescence modulation/switching both in solution and in the solid state.
Funder
National Natural Science Foundation of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT03239H
Reference26 articles.
1. Versatile Control of Directed Supramolecular Assembly via Subtle Changes of the Rhodium(I) Pincer Building Blocks
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3. Modulation of Metallophilic Bonds: Solvent-Induced Isomerization and Luminescence Vapochromism of a Polymorphic Au–Cu Cluster
4. Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced Reverse Single-Crystal-to-Single-Crystal Phase Transitions with Alterations of the Luminescence Color
5. Stimuli-Responsive Solvatochromic Au(I)–Ag(I) Clusters: Reactivity and Photophysical Properties Induced by the Nature of the Solvent
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2. Synthesis and structural characterization of bis-cyclometalated compounds [Ir(dFppy)2(Me4phen)]PF6 and [Ir(dF(CF3)ppy)2(Me4phen)]PF6;Inorganica Chimica Acta;2021-11
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