Insights into the physical chemistry of materials from advances in HAADF-STEM

Abstract

HAADF-STEM provides atomic-resolution real space imaging. Here an image of a single Si dopant atom in a graphene lattice is shown adjacent to a schematic of the instrument. Simultaneous EELS on electrons scattered to low angles can provide chemical identification of the species preset. Differences between the Si L-edge spectra reveal differences in atomic bonding and hybridization for different configurations of Si atoms in graphene.