Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment-Reference-Cited by-同舟云学术

Manganese phosphinocarbodithioate for RAFT polymerisation with sunlight-induced chain end post-treatment

Published:2019 Issue:2 Volume:10 Page:267-277
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Kulai Ihor¹²³⁴⁵^ORCID,Karpus Andrii¹²³⁴⁵^ORCID,Soroka Liubov¹²³⁴⁵,Valyaev Dmitry A.⁶⁷⁸⁹¹⁰^ORCID,Bourdon Valérie¹¹⁴⁵,Manoury Eric⁶⁷⁸⁹¹⁰^ORCID,Poli Rinaldo⁶⁷⁸⁹¹⁰^ORCID,Destarac Mathias¹²³⁴⁵^ORCID,Mazières Stéphane¹²³⁴⁵^ORCID

Affiliation:

1. Laboratoire des IMRCP

2. Université Paul Sabatier

3. CNRS UMR 5623

4. 31062 Toulouse

5. France

6. CNRS

7. LCC (Laboratoire de Chimie de Coordination)

8. Université de Toulouse

9. UPS

10. INPT

11. ICT – Service de spectrométrie de masse – Université Paul Sabatier

Abstract

A new manganese complex of the formula Cp(CO)₂MnP(Ph)₂C(S)SCH(CH₃)Ph is an efficient RAFT agent for the preparation of SH-terminated polymers by simple visible light photocleavage of the organometallic end-group.

Funder

Agence Nationale de la Recherche

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2019/PY/C8PY01279B

Reference55 articles.

1. Living Radical Polymerization by the RAFT Process – A Third Update

2. Thiocarbonylthio Compounds (SC(Z)S−R) in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization). Effect of the Activating Group Z

3. Thiocarbonylthio Compounds [SC(Ph)S−R] in Free Radical Polymerization with Reversible Addition-Fragmentation Chain Transfer (RAFT Polymerization). Role of the Free-Radical Leaving Group (R)