Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes-Reference-Cited by-同舟云学术

Intramolecular Friedel–Crafts alkylation with a silylium-ion-activated cyclopropyl group: formation of tricyclic ring systems from benzyl-substituted vinylcyclopropanes and hydrosilanes

Published:2021 Issue:2 Volume:12 Page:569-575
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

He Tao¹²³⁴^ORCID,Wang Guoqiang¹²³⁴^ORCID,Long Peng-Wei¹²³⁴^ORCID,Kemper Sebastian¹²³⁴^ORCID,Irran Elisabeth¹²³⁴^ORCID,Klare Hendrik F. T.¹²³⁴^ORCID,Oestreich Martin¹²³⁴^ORCID

Affiliation:

1. Institut für Chemie

2. Technische Universität Berlin

3. 10623 Berlin

4. Germany

Abstract

Downstream to alkene hydrosilylation, the opening of the cyclopropane ring in benzyl-substituted VCPs is interlinked with an S_EAr of the aryl group.

Funder

China Scholarship Council

Einstein Stiftung Berlin

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05553K

Reference42 articles.

1. Silylium-Ion-Promoted Ring-Opening Hydrosilylation and Disilylation of Unactivated Cyclopropanes

2. B(C6F5)3-Catalyzed Hydrosilylation of Vinylcyclopropanes

3. Silylium‐Ion‐Promoted (5+1) Cycloaddition of Aryl‐Substituted Vinylcyclopropanes and Hydrosilanes Involving Aryl Migration

4. D. Weber and M. R.Gagné , in Organosilicon Chemistry: Novel Approaches and Reactions , ed. T. Hiyama and M. Oestreich , Wiley-VCH , Weinheim , 2019 , pp. 33–85

5. A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

Cited by 20 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Trityl tetrakis(pentafluorophenyl)borate: A sustainable precursor for multifunctional silylium Lewis acid organocatalysis;Chem Catalysis;2024-04

2. Heterodifunctionalization of Electron-Rich Alkynes Catalyzed by in Situ Generated Silylium Ions;Organic Letters;2024-01-02

3. Application of Triaryl Carbenium in Organic Synthesis;Chinese Journal of Organic Chemistry;2024

4. Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions;Synlett;2023-10-09

5. Nickel-Catalyzed Reductive [4 + 1] Sila-Cycloaddition of 1,3-Dienes with Dichlorosilanes;Journal of the American Chemical Society;2023-06-07