Heterobimetallic Ba/Li and Ca/Li amides and diphenylmethanide
Author:
Affiliation:
1. Univ Rennes
2. CNRS
3. ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226
4. F-35000 Rennes
5. France
Abstract
Rare examples of stable heterobimetallic Ca/Li and Ba/Li amido polymeric species, as well as an ate Ca/Li diphenylmethanide compound stable in ethers, have been structurally characterised. Intra- and intermolecular metal⋯H–Si interactions are shown to play a key role.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT00771G
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