Titanium isopropoxide-mediated <i>cis</i>-selective synthesis of 3,4-substituted butyrolactones from CO<sub>2</sub>-Reference-Cited by-同舟云学术

Titanium isopropoxide-mediated cis-selective synthesis of 3,4-substituted butyrolactones from CO₂

Published:2022 Issue:18 Volume:58 Page:3027-3030
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Sahari Aleksi¹^ORCID,Do Cuong Dat²^ORCID,Mannisto Jere K.¹^ORCID,Antico Emanuele¹^ORCID,Amaratunga Angelo¹^ORCID,Hopmann Kathrin H.³^ORCID,Repo Timo¹^ORCID

Affiliation:

1. Department of Chemistry, University of Helsinki, FI-00014 University of Helsinki, Finland

2. Hylleraas Center for Quantum Molecular Sciences, Department of Chemistry, UiT The Arctic University of Norway, 9037 Tromsø, Norway

3. Department of Chemistry, UiT The Arctic University of Norway, 9037 Tromsø, Norway

Abstract

Titanium-mediated 1,2-activation of Grignard reagents enables α and β insertion of carbon dioxide and arylaldehyde to prepare cis-3,4 butyrolactones.

Funder

NordForsk

Norges Forskningsråd

Tromsø Forskningsstiftelse

Helsingin Yliopisto

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/CC/D2CC00446A

Reference27 articles.

1. Beyond Aresta’s Complex: Ni- and Pd-Catalyzed Organozinc Coupling with CO2

2. Ni-Catalyzed Direct Carboxylation of Benzyl Halides with CO2

3. Using carbon dioxide as a building block in organic synthesis

4. Transition metal-catalyzed carboxylation of unsaturated substrates with CO2

5. Recent advances in nucleophile-triggered CO2-incorporated cyclization leading to heterocycles

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