Silver-catalysed [3 + 2] annulation reaction of aryldiazonium salts with allenes enabled by boronate direction

Author:

Peng Xing1,Zheng Meng-Meng2,Qin Pei1,Xue Xiao-Song23ORCID,Zhang Fa-Guang1ORCID,Ma Jun-An1ORCID

Affiliation:

1. Department of Chemistry, Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Frontiers Science Center for Synthetic Biology (Ministry of Education), and Tianjin Collaborative Innovation Centre of Chemical Science & Engineering, Tianjin University, Tianjin 300072, P. R. China

2. State Key Laboratory of Elemento-organic Chemistry, Nankai University, Tianjin 300071, P. R. China

3. Key Laboratory of Organofluorine Chemistry, Shanghai Institute of Organic Chemistry, University of Chinese Academy of Sciences, Chinese Academy of Sciences, 345 Lingling Road, Shanghai 200032, P. R. China

Abstract

The applicability of allenylboronates as novel all-carbon formal 1,3-dipoles in the silver-catalysed annulation reaction with aryldiazonium salts for the synthesis of N-aryl pyrazoles is disclosed.

Funder

National Key Research and Development Program of China

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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