Oxygenation of RZn(N,O)-type complexes as an efficient route to zinc alkoxides not accessible via the classical alcoholysis path-Reference-Cited by-同舟云学术

Oxygenation of RZn(N,O)-type complexes as an efficient route to zinc alkoxides not accessible via the classical alcoholysis path

Published:2017 Issue:78 Volume:53 Page:10808-10811
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Wróbel Zbigniew¹²³⁴⁵,Pietrzak Tomasz⁶⁷⁵,Justyniak Iwona¹²³⁴⁵,Lewiński Janusz¹²³⁴⁵^ORCID

Affiliation:

1. Institute of Physical Chemistry

2. Polish Academy of Sciences

3. Kasprzaka 44/52

4. Warsaw 01-224

5. Poland

6. Department of Chemistry, Warsaw University of Technology, Noakowskiego 3

7. Warsaw 00-664

Abstract

The oxygenation of alkylzincs incorporating a 2-ester substituted pyrrolate ligand (L) leads to zinc alkoxides with an uncommon structural motif in the solid state: a trimer [(L)Zn(μ-O^tBu)]₃ with the central [Zn₃(μ-OR)₃] ring or a heterocubane [(L)Zn(μ₃-OEt)]₄.

Funder

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2017/CC/C7CC05818G

Reference53 articles.

1. Zinc Oxide Nanoparticles with Defects

2. On the Role of Oxygen Defects in the Catalytic Performance of Zinc Oxide

3. Self-Assembly of Methylzinc–Polyethylene Glycol Amphiphiles and Their Application to Materials Synthesis

4. tert-Butyl(tert-butoxy)zinc Hydroxides: Hybrid Models for Single-Source Precursors of ZnO Nanocrystals

5. Biocompatible Initiators for Lactide Polymerization

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