Photocatalytic selectivity switch to C–C scission: α-methyl ejection oftert-butanol on TiO2(110)
Author:
Affiliation:
1. Chair of Physical Chemistry
2. Department of Chemistry and Catalysis Research Center
3. Technische Universität München
4. 85748 Garching
5. Germany
Abstract
The thermal and photochemical mechanistic pathways for tertiary alcohols on the rutile TiO2(110)-surface are studied with the example oftert-butanol.
Funder
Deutsche Forschungsgemeinschaft
Publisher
Royal Society of Chemistry (RSC)
Subject
Physical and Theoretical Chemistry,General Physics and Astronomy
Link
http://pubs.rsc.org/en/content/articlepdf/2018/CP/C8CP00223A
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