Supramolecular self-assembled coordination architecture composed of a doubly bis(2-pyridyl)pyrazolate bridged dinuclear CuII complex and 7,7′,8,8′,-tetracyano-p-quinodimethanide radicals

Abstract

A tetranuclear Cu^II complex composed of a doubly bpypz⁻ bridged dinuclear Cu^II complex with TCNQ˙⁻ self-assembles into a 3D supramolecular coordination architecture via complementary weak coordination bonding and π-stacking interactions.