Low temperature (550–700 K) oxidation pathways of cyclic ketones: dominance of HO2-elimination channels yielding conjugated cyclic coproducts-Reference-Cited by-同舟云学术

Low temperature (550–700 K) oxidation pathways of cyclic ketones: dominance of HO2-elimination channels yielding conjugated cyclic coproducts

Published:2015 Issue:18 Volume:17 Page:12124-12134
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Scheer Adam M.¹²³⁴,Welz Oliver¹²³⁴^ORCID,Vasu Subith S.¹²³⁴,Osborn David L.¹²³⁴,Taatjes Craig A.¹²³⁴

Affiliation:

1. Combustion Research Facility

2. Sandia National Laboratories

3. Livermore

4. USA

Abstract

The low-temperature oxidation of three cyclic ketones, cyclopentanone (CPO; C₅H₈O), cyclohexanone (CHO; C₆H₁₀O), and 2-methyl-cyclopentanone (2-Me-CPO; CH₃–C₅H₇O), is studied between 550 and 700 K and at 4 or 8 Torr total pressure.

Funder

National Nuclear Security Administration

Laboratory Directed Research and Development

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2015/CP/C4CP06097K

Reference31 articles.

1. How biotech can transform biofuels

2. Fractionating recalcitrant lignocellulose at modest reaction conditions

3. Biomass Recalcitrance: Engineering Plants and Enzymes for Biofuels Production

4. J. M. Gladden , C. A.Taatjes, C.Gao, G.O’Bryan, A. J.Powell, A. M.Scheer, K.Turner, W.Wu and E. T.Yu, Tailoring Next-Generation Biofuels and their Combustion in Next-Generation Engines, Report SAND2013-10094, Sandia National Laboratories, Livermore, California, 2013

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