Anchoring a bow-shaped boron single chain in binary Be6B7− cluster: hybrid octagonal ring, multifold π/σ aromaticity, and dual electronic transmutation-Reference-Cited by-同舟云学术

Anchoring a bow-shaped boron single chain in binary Be6B7− cluster: hybrid octagonal ring, multifold π/σ aromaticity, and dual electronic transmutation

Published:2020 Issue:44 Volume:22 Page:25574-25583
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Feng Lin-Yan¹²³⁴⁵,Wang Kang¹²³⁴⁵,Zhai Hua-Jin¹²³⁴⁵^ORCID

Affiliation:

1. Nanocluster Laboratory

2. Institute of Molecular Science

3. Shanxi University

4. Taiyuan 030006

5. China

Abstract

A bow-shaped B₇ single chain motif is stabilized in binary Be₆B₇⁻ cluster, which undergoes dual electronic transmutation, being governed by multifold 1σ/10π/6σ/1σ aromaticity.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP05012A

Reference75 articles.

1. The Boranes and Their Relatives

2. Collision-induced dissociation and ab initio studies of boron cluster ions: determination of structures and stabilities

3. SystematicLSD investigation on cationic boron clusters: Bn+(n ? 2-14)