Challenging cross couplings, in water, aided by <i>in situ</i> iodination of (hetero)aromatic bromides-Reference-Cited by-同舟云学术

Challenging cross couplings, in water, aided by in situ iodination of (hetero)aromatic bromides

Published:2023 Issue:46 Volume:14 Page:13503-13507
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Thomas Rohan M.¹^ORCID,Obbard David B.¹,Lipshutz Bruce H.¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, University of California, Santa Barbara, CA 93106, USA

Abstract

Palladium-catalyzed reactions that involve functionalized substrates are oftentimes problematic. An initial Br-to-I conversion followed by an immediate cross coupling may allow for the targeted C–C bonds to be obtained.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/SC/D3SC04199A

Reference22 articles.

1. Pharmaceutical diversification via palladium oxidative addition complexes

2. Copper-catalysed aromatic-Finkelstein reactions with amine-based ligand systems

3. Copper-Catalyzed Halogen Exchange in Aryl Halides: An Aromatic Finkelstein Reaction

4. Total Syntheses of the Tylophora Alkaloids Cryptopleurine, (−)-Antofine, (−)-Tylophorine, and (−)-Ficuseptine C

5. Total synthesis of (±)-aspercyclide A and its C19 methyl ether

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