Beryllium compounds for the carbon–halogen bond activation of phenyl halides: the role of non-innocent ligands-Reference-Cited by-同舟云学术

Beryllium compounds for the carbon–halogen bond activation of phenyl halides: the role of non-innocent ligands

Published:2023 Issue:37 Volume:52 Page:13068-13078
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Trujillo-González Daniel E.¹²^ORCID,González-García Gerardo¹^ORCID,Jiménez-Halla J. Oscar C.¹,Solà Miquel²^ORCID

Affiliation:

1. Departamento de Química, Campus Guanajuato, Universidad de Guanajuato, Noria Alta S/N, CP 36050, Guanajuato, Gto, Mexico

2. Institut de Química Computacional i Catàlisi and Departament de Química, Universitat de Girona, C/ Maria Aurèlia Capmany, 69, 17003 Girona, Catalonia, Spain

Abstract

A detailed DFT mechanistic study is presented to describe the phenyl–halogen bond activation mediated by five-membered heterocyclic Be(ii) bidentate ligands and (CAAC)2Be. Our study highlights the key role played by the ligands in this process.

Funder

Universidad de Guanajuato

Departament d'Innovació, Universitats i Empresa, Generalitat de Catalunya

Consejo Nacional de Ciencia y Tecnología

Ministerio de Ciencia e Innovación

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/DT/D3DT02251J

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