A conjugated Schiff-base macrocycle weakens the transverse crystal field of air-stable dysprosium single-molecule magnets-Reference-Cited by-同舟云学术

A conjugated Schiff-base macrocycle weakens the transverse crystal field of air-stable dysprosium single-molecule magnets

Published:2022 Issue:19 Volume:9 Page:4982-4989
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Liu Shuting¹²,Gil Yolimar³^ORCID,Zhao Chen¹²^ORCID,Wu Jinjiang¹²,Zhu Zhenhua¹^ORCID,Li Xiao-Lei¹^ORCID,Aravena Daniel⁴^ORCID,Tang Jinkui¹²^ORCID

Affiliation:

1. State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, P. R. China

2. School of Applied Chemistry and Engineering, University of Science and Technology of China, Hefei 230026, P. R. China

3. Facultad de Ciencias Químicas y Farmacéuticas, Universidad de Chile, Casilla 233, Santiago, Chile

4. Departamento de Química de los Materiales, Facultad de Química y Biología, Universidad de Santiago de Chile, Casilla 40, Correo 33, Santiago, Chile

Abstract

The dominance of a self-condensed conjugated macrocycle over a [2 + 2] conventional macrocycle in weakening the transverse crystal field and boosting axiality provides a new route to construct high-performance air-stable lanthanide SMMs.

Funder

Key Research Program of Frontier Science, Chinese Academy of Sciences

Chinese Academy of Sciences

National Science and Technology Major Project

Royal Society

Fondo Nacional de Desarrollo Científico y Tecnológico

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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