New aspect of photophysics of 7,7,8,8-tetracyanoquinodimethane and its solvated complexes: intra- vs. inter-molecular charge-transfer-Reference-Cited by-同舟云学术

New aspect of photophysics of 7,7,8,8-tetracyanoquinodimethane and its solvated complexes: intra- vs. inter-molecular charge-transfer

Published:2021 Issue:36 Volume:11 Page:22381-22389
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Muramatsu Satoru¹²³⁴⁵^ORCID,Chaki Nobumasa¹²³⁴⁵,Kinoshita Shin-nosuke¹²³⁴⁵,Inokuchi Yoshiya¹²³⁴⁵^ORCID,Abe Manabu¹²³⁴⁵^ORCID,Iimori Toshifumi⁶⁷⁸⁵^ORCID,Ebata Takayuki¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Advanced Science and Engineering

3. Hiroshima University

4. Hiroshima

5. Japan

6. Department of Sciences and Informatics

7. Muroran Institute of Technology

8. Muroran

Abstract

We show that 7,7,8,8-tetracyanoquinodimethane (TCNQ) has both intra- and inter-molecular charge-transfer states. They appear in a different manner in the fluorescence, sensitively depending on the nature of solvent molecules.

Funder

Japan Society for the Promotion of Science

Ministry of Science and Technology, Taiwan

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA01430G

Reference29 articles.

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2. Electron transfer in a new highly conducting donor-acceptor complex

3. Iron Pentacarbonyl as a Precursor for Molecule-Based Magnets: Formation of Fe[TCNE]2 (Tc = 100 K) and Fe[TCNQ]2 (Tc = 35 K) Magnets

4. Molecular Electrical Doping of Organic Semiconductors: Fundamental Mechanisms and Emerging Dopant Design Rules

5. Band-Like Carrier Transport at the Single-Crystal Contact Interfaces between 2,5-Difluoro-7,7,8,8-tetracyanoquinodimethane and Electron Donors

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