Two-dimensional Cd3-based metal–organic frameworks with halogen bonding sites for the uptake of I2

Author:

Zhang Zhi-Hao1,Ge Jia-Lu2,Li Yan1,Li Qing1,Ma Pin-Pin1,Tang Xiao-Yan2ORCID,Zhang Wen-Hua1ORCID,Young David J.3ORCID

Affiliation:

1. College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China

2. School of Materials Engineering, Changshu Institute of Technology, Changshu, China

3. College of Engineering, Information Technology & Environment, Charles Darwin University, Darwin, Northern Territory 0810, Australia

Abstract

The coordinated DEF solvates of a 2D MOF were replaced by pyrazine, 3-cyanopyridine, and 4-cyanopyridine to yield isoreticular structures with enhanced I2uptake because of the introduction of halogen-bonding sites.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry

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