HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes-Reference-Cited by-同舟云学术

HCOOH disproportionation to MeOH promoted by molybdenum PNP complexes

Published:2021 Issue:39 Volume:12 Page:13101-13119
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Alberico Elisabetta¹²^ORCID,Leischner Thomas¹,Junge Henrik¹^ORCID,Kammer Anja¹,Sang Rui¹^ORCID,Seifert Jenny¹,Baumann Wolfgang¹,Spannenberg Anke¹,Junge Kathrin¹^ORCID,Beller Matthias¹^ORCID

Affiliation:

1. Leibniz-Institut für Katalyse e. V., Albert-Einstein Straße 29a, 18059 Rostock, Germany

2. Istituto di Chimica Biomolecolare, Consiglio Nazionale delle Ricerche, tr. La Crucca 3, 07100 Sassari, Italy

Abstract

Mo(0) complexes with aliphatic PNP-pincer ligands enable the first example of non-noble metal catalyzed formic acid disproportionation leading to methanol with a selectivity of up to 37% and a turnover number up to 69.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC04181A

Reference133 articles.

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