A combined experimental and DFT mechanistic study for the unexpected nitrosolysis of N-hydroxymethyldialkylamines in fuming nitric acid-Reference-Cited by-同舟云学术

A combined experimental and DFT mechanistic study for the unexpected nitrosolysis of N-hydroxymethyldialkylamines in fuming nitric acid

Published:2018 Issue:34 Volume:8 Page:19310-19316
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Zhang Yu¹²³⁴,Zou Po¹²³⁴,Han Yingbin¹²³⁴,Geng Yongliang¹²³⁴,Luo Jun¹²³⁴^ORCID,Zhou Baojing¹²³⁴

Affiliation:

1. School of Chemical Engineering

2. Nanjing University of Science and Technology

3. Nanjing 210094

4. China

Abstract

N-Hydroxymethyldialkylamines were nitrosolyzed unexpectedly in fuming HNO₃ to give N-nitrosamines. A mechanism involving a redox reaction of HNO₃ was proposed and DFT calculations indicated that the reaction proceeded smoothly with a rigid bicyclic transition state.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2018/RA/C8RA03268H

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