Facet-dependent carrier dynamics of cuprous oxide regulating the photocatalytic hydrogen generation

Author:

Toe Cui Ying1ORCID,Lamers Marlene2,Dittrich Thomas3,Tahini Hassan A.4,Smith Sean C.4,Scott Jason1ORCID,Amal Rose1ORCID,van de Krol Roel2ORCID,Abdi Fatwa F.2ORCID,Ng Yun Hau15ORCID

Affiliation:

1. Particles and Catalysis Research Group, School of Chemical Engineering, The University of New South Wales, NSW 2052, Australia

2. Institute for Solar Fuels, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Hahn-Meitner-Platz 1, Berlin 14109, Germany

3. Institute for Silicon Photovoltaics, Helmholtz-Zentrum Berlin für Materialien und Energie GmbH, Kekuléstrasse 5, Berlin 12489, Germany

4. Research School of Physics and Engineering, The Australian National University, Canberra, ACT 2601, Australia

5. School of Energy and Environment, City University of Hong Kong, Kowloon, Hong Kong SAR, P. R. China

Abstract

The photoactivity of rhombic dodecahedral Cu2O with dominant {110} facets is superior to that of cubic Cu2O with {100} surfaces partly owing to the improved charge separation and carrier mobility.

Funder

Research Grants Council, University Grants Committee

Australian Research Council

Publisher

Royal Society of Chemistry (RSC)

Subject

General Materials Science,Chemistry (miscellaneous)

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