Strategies for breaking molecular scaling relationships for the electrochemical CO<sub>2</sub> reduction reaction-Reference-Cited by-同舟云学术

Strategies for breaking molecular scaling relationships for the electrochemical CO₂ reduction reaction

Published:2022 Issue:18 Volume:51 Page:6993-7010
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Nie Weixuan¹^ORCID,McCrory Charles C. L.¹²^ORCID

Affiliation:

1. Department of Chemistry, University of Michigan, Ann Arbor, Michigan, 48109-1055, USA

2. Macromolecular Science and Engineering Program, University of Michigan, Ann Arbor, Michigan, 48109-1055, USA

Abstract

For CO2 reduction by molecular catalysts, beneficial decreases in overpotential (ηeff) are often correlated with detrimental decreases in activity (TOFmax). This perspective explores design strategies to break these molecular scaling relationships.

Funder

Basic Energy Sciences

Horace H. Rackham School of Graduate Studies, University of Michigan

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/DT/D2DT00333C

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