A new porous Co(ii)-metal–organic framework for high sorption selectivity and affinity to CO2 and efficient catalytic oxidation of benzyl alcohols to benzaldehydes-Reference-Cited by-同舟云学术

A new porous Co(ii)-metal–organic framework for high sorption selectivity and affinity to CO2 and efficient catalytic oxidation of benzyl alcohols to benzaldehydes

Published:2021 Issue:20 Volume:23 Page:3717-3723
ISSN:1466-8033
Container-title:CrystEngComm
language:en
Short-container-title:CrystEngComm

Author:

Wu Yun-Long¹²³⁴⁵^ORCID,Yang Rong-Rong¹²³⁴,Yang Guo-Ping⁵⁶⁷⁸⁹^ORCID,Yan Yang-Tian¹²³⁴,Su Xiao-Lei¹²³⁴,He Xin-Hai¹²³⁴,Song Yan-Yan¹²³⁴,Ma Zheng-Sheng⁵⁶⁷⁸⁹,Wang Yao-Yu⁵⁶⁷⁸⁹^ORCID

Affiliation:

1. School of Materials Science & Engineering

2. Xi'an Polytechnic University

3. Xi'an 710048

4. P. R. China

5. Key Laboratory of Synthetic and Natural Functional Molecule of Ministry of Education

6. Shaanxi Key Laboratory of Physico-Inorganic Chemistry

7. College of Chemistry & Materials Science, and

8. School of Chemical Engineering

9. Northwest University

Abstract

A new porous Co(ii)-MOF I has been prepared. Gas sorption and catalytic experiments show that the guest-free sample I′ shows the high capacity and selectivity to CO₂ over CH₄ and catalytically oxidize benzyl alcohols efficiently into benzaldehydes.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Shaanxi Province

Education Department of Shaanxi Province

China Postdoctoral Science Foundation

Xi'an Polytechnic University

Shaanxi Science and Technology Association

Key Laboratory of Synthetic and Natural Functional Molecular Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Condensed Matter Physics,General Materials Science,General Chemistry