N-heterocyclic phosphenium and phosphido nickel complexes supported by a pincer ligand framework-Reference-Cited by-同舟云学术

N-heterocyclic phosphenium and phosphido nickel complexes supported by a pincer ligand framework

Published:2016 Issue:5 Volume:45 Page:1918-1929
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Evers-McGregor Deirdra A.¹²³⁴,Bezpalko Mark W.¹²³⁴,Foxman Bruce M.¹²³⁴,Thomas Christine M.¹²³⁴

Affiliation:

1. Department of Chemistry

2. Brandeis University

3. Waltham

4. USA

Abstract

A tridentate ligand framework containing a central N-heterocyclic phosphenium cation (NHP⁺) has been coordinated to nickel. Among the compounds reported is a series of [(PPP)Ni]₂^0/+/2+ dimers in three different redox states.

Funder

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C5DT03549J

Reference61 articles.

1. Synthesis of a cyclic fluorodialkylaminophosphine and its coordination with boron acids. Formation of a unique dialkylaminophosphine cation

2. Cationic low coordinated phosphorus compounds as ligands: Recent developments

3. Cation Stabilities, Electrophilicities, and “Carbene Analogue” Character of Low Coordinate Phosphorus Cations

4. Stability and Electrophilicity of Phosphorus Analogues of Arduengo Carbenes—An Experimental and Computational Study

5. Ab Initio MO Study on Cationic Phosphenium Complexes of Group 6 Transition Metals, fac- and mer-[(bpy)(CO)3M{PN(Me)CH2CH2NMe}]+ (M = Mo, W)

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