Influence of uranyl complexation on the reaction kinetics of the dodecane radical cation with used nuclear fuel extraction ligands (TBP, DEHBA, and DEHiBA)-Reference-Cited by-同舟云学术

Influence of uranyl complexation on the reaction kinetics of the dodecane radical cation with used nuclear fuel extraction ligands (TBP, DEHBA, and DEHiBA)

Published:2021 Issue:43 Volume:23 Page:24589-24597
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Celis Barros Cristian¹^ORCID,Pilgrim Corey D.²^ORCID,Cook Andrew R.³^ORCID,Mezyk Stephen P.⁴^ORCID,Grimes Travis S.²^ORCID,Horne Gregory P.²^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, FL 32306, USA

2. Center for Radiation Chemistry Research, Idaho National Laboratory, P.O. Box 1625, Idaho Falls, ID, 83415, USA

3. Department of Chemistry, Brookhaven National Laboratory, Upton, New York, 11973, USA

4. Department of Chemistry and Biochemistry, California State University Long Beach, 1250 Bellflower Boulevard, Long Beach, California, 90840-9507, USA

Abstract

Used nuclear fuel uranium complexants (TBP, DEHBA, and DEHiBA) exhibit significantly different radiation-induced reactivities upon uranyl complexation as dictated by a combination of electron density distribution and reaction pathway energetics.

Funder

U.S. Department of Energy

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2021/CP/D1CP03797H

Reference49 articles.

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