Effect of electron structure on the catalytic activity of LaCoO3 perovskite towards toluene oxidation

Author:

Chen Hanlin1234,Liu Peng124,Wei Gaoling5,Huang Yu6ORCID,Lin Xiaoju124,Liang Xiaoliang124ORCID,Zhu Jianxi124ORCID

Affiliation:

1. CAS Key Laboratory of Mineralogy and Metallogeny/Guangdong Provincial Key Laboratory of Mineral Physics and Materials, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, P. R. China

2. CAS Center for Excellence in Deep Earth Science, Guangzhou, 510640, China

3. School of Environmental Science and Technology, Guangdong University of Petrochemical Technology, Maoming 525000, P. R. China

4. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

5. National-Regional Joint Engineering Research Center for Soil Pollution Control and Remediation in South China, Guangdong Key Laboratory of Integrated Agro-environmental Pollution Control and Management, Institute of Eco-environmental and Soil Sciences, Guangdong Academy of Sciences, Guangzhou 510650, China

6. Key Laboratory of Aerosol Chemistry and Physics, State Key Lab of Loess and Quaternary Geology (SKLLQG), Institute of Earth Environment, Chinese Academy of Sciences, Xi'an 710061, P. R. China

Abstract

The catalytic activity of LaCoO3 perovskite towards toluene oxidation is closely associated with the electron structure (e.g., eg electron filling and O p-band center).

Funder

National Natural Science Foundation of China

Guangdong Science and Technology Department

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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