Solution structures of alkali metal cyclopentadienides in THF estimated by ECC-DOSY NMR-spectroscopy (incl. software)

Author:

Bachmann Sebastian123,Gernert Björn4563,Stalke Dietmar123

Affiliation:

1. Institut für Anorganische Chemie

2. Georg-August-Universität

3. Germany

4. Institut für Betriebssysteme und Rechnerverbund

5. TU Braunschweig

6. Braunschweig

Abstract

In this paper we present the aggregational motifs of the widely used alkali-metal cyclopentadienides (CpLi, CpNa, CpK, CpRb, CpCs) in THF-d8 solution estimated by ECC-DOSY NMR spectroscopy.

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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3. η5,η1-Coordinated cyclopentadienyl transition metal complexes featuring σ-metal–carbon ansa bridges

4. T. Stey and D.Stalke, Lead structures in lithium organic chemistry in The chemistry of organolithium compounds, ed., Z. Rappoport and I. Marek, John Wiley & Sons, New York, 2004, pp. 47–120

5. Ueber Ketonreactionen bei dem Cyclopentadiën

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