Mixed-ligand lanthanide complexes supported by ditopic bis(imino-methyl)-phenol/calix[4]arene macrocycles: synthesis, structures, and luminescence properties of [Ln2(L2)(MeOH)2] (Ln = La, Eu, Tb, Yb)

Author:

Ullmann Steve12345,Hahn Peter1234,Mini Parvathy6789,Tuck Kellie L.6789ORCID,Kahnt Axel1011124ORCID,Abel Bernd101112413ORCID,Gutierrez Suburu Matias E.141516174ORCID,Strassert Cristian A.141516174ORCID,Kersting Berthold1234ORCID

Affiliation:

1. Institut für Anorganische Chemie

2. Universität Leipzig

3. 04103 Leipzig

4. Germany

5. Institut für Nichtklassiche Chemie e.V.

6. School of Chemistry

7. Monash University

8. Clayton

9. Australia

10. Leibniz Institute of Surface Engineering (IOM)

11. Department of Functional Surfaces

12. Permoserstr. 15, D-04318 Leipzig

13. Wilhelm-Ostwald-Institut für Physikalische und Theoretische Chemie

14. Institut für Anorganische und Analytische Chemie

15. CiMIC

16. SoN - Westfälische Wilhelms-Universität Münster

17. 48149 Münster

Abstract

H6L2 was found to be an effective dinucleating ligand for various Ln3+ ions forming luminescent, mixed-ligand complexes of composition [Ln2(L2)(MeOH)2] with one exchangeable coligand per seven-coordinated Ln site.

Funder

Deutsche Forschungsgemeinschaft

Deutscher Akademischer Austauschdienst

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Reference75 articles.

1. J.-C. G. Bünzli and S.Eliseeva , Basics of Lanthanide Photophysics , in Lanthanide Luminescence , ed. P. Hänninen and H. Härmä , Springer Berlin Heidelberg , Berlin , 2011 , vol. 7 , pp. 1–45

2. Rational Design of Sequestering Agents for Plutonium and Other Actinides

3. Anion binding in water at lanthanide centres: from structure and selectivity to signalling and sensing

4. Lanthanide complexes for luminescence-based sensing of low molecular weight analytes

5. D. Gutsche , Calixarenes: An Introduction , RSC Publishing , Cambridge , 2nd edn, 2008

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